Vinegar as a preservative works in much the same way as the lactic acid produced by bacteria during fermentation. The acetic acid in the vinegar acts to kill harmful microorganisms and then keep others out. The percentage of the vinegar in the final solution is also important because a certain percentage is needed in order to achieve proper preservation.
For most pickles, either fermented or vinegared, heat needs to be applied to make the final product shelf stable (often to achieve a vacuum in the jar). This can either be done in a pressure canner, boiling water bath, or low temperature pasteurization.
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